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Experimental
Test of Self-Shielding in VUV Photodissociation of CO
One way to test models of the solar system's
formation is to compare the isotopic abundances of the elements
found in its constituent bodies. A case in point is oxygen with
three stable isotopes dominated by oxygen-16, with minute fractions
of oxygen-17 and oxygen-18. Primitive objects whose formation
predates the Earth's, such as the calcium-aluminum-rich inclusions
in the Allende meteorite, have relatively higher fractions of
the two heavier isotopes than does the Earth’s crust. Among
the numerous explanations that have been proposed is the notion
that chemical processes within the early solar nebula gave rise
to the oxygen ratios, a leading candidate being a process called
isotope self-shielding. But researchers from the University of
California, San Diego, and Berkeley Lab have now shown that photodissociation
of carbon monoxide (CO) caused by vacuum-ultraviolet (VUV) light
from the early sun could generate reservoirs of the heavier isotopes
in the solar nebula without the help of self-shielding. Full
story.

Publication about this research: S. Chakraborty,
M. Ahmed, T.L. Jackson, and M.H. Thiemens, "Experimental
test of self-shielding in vacuum ultraviolet photodissociation
of CO," Science 321, 1328 (2008).
Mark H. Thiemens |
Self-Assembly
of Polymer Nano-Elements on Sapphire
Self-assembly of polymers promises to vastly
improve the properties and manufacturing processes of nanostructured
materials, since self-assembly is highly parallel, quite versatile,
and easy to implement. Especially promising are novel compounds
known as block copolymers, formed by two chemically different
polymers that are linked together. Guided patterned arrays have
been produced using electron-beam lithographic techniques or
nano-imprint lithography, but these methods are painstaking,
and they have not yet been able to produce perfect surfaces over
large areas. Recently, a group of researchers used faceted surfaces
of commercially available sapphire wafers to guide the self-assembly
of block copolymer microdomains. Grazing-incidence small-angle
x-ray scattering (GISAXS) at ALS Beamline 7.3.3 verified the
arrays' quasi long-range crystalline order over arbitrarily large
wafer surfaces. It's expected that this new method of producing
highly ordered macroscopic arrays of nanoscopic elements will
revolutionize the microelectronic and storage industries and
perhaps others, such as photovoltaics. Full
story.

Publication about this research: S. Park, D.H.
Lee, J. Xu, B. Kim, S.W. Hong, U. Jeong, T. Xu, and T.P. Russell, "Macroscopic
10-terabit-per-square-inch arrays from block copolymers with
lateral order," Science 323, 1030 (2009).
Thomas Russell
Ting Xu
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New
Responsibilities for Falcone, Schoenlein, Oddone
ALS
Division Director Roger Falcone has been appointed by Berkeley
Lab's Interim Director Paul Alivisatos to serve as Associate
Laboratory Director for Photon Sciences. In this position, Roger
will continue to serve as ALS director, leading efforts to renew
the ALS while working to secure the Next Generation Light Source
at Berkeley Lab. The Next Generation Light Source has the potential
to revolutionize energy science research and is a critical project
for the future of Berkeley Lab. Alivisatos also appointed Environmental
Energy Technology Division Director Arun Majumdar to serve as
Associate Laboratory Director for Energy and Environment. In
a videotaped announcement, Alivisatos said: "These
are exciting times for Berkeley Lab. Together, we are pursuing
new large-scale science and technology initiatives for energy
and environment, topics that are more relevant than ever to the
health and prosperity of our nation and the planet... Please
join me in thanking Roger and Arun for assuming these additional
responsibilities, which are effective immediately. Both are outstanding
scientists and have served this Lab with distinction. The Lab
will be stronger for their strength and vision."
Also
this month, Roger announced that Bob Schoenlein is joining the
ALS as Deputy Director for Science. Bob is a scientist with the
Materials Sciences Division at Berkeley Lab and is well known
to many at the ALS as the developer of Beamline 6, our ultrafast
x-ray facility, and an expert in condensed-phase physics. He
has worked on projects ranging from the dynamics of biomolecules
to the understanding of complex oxides and with photons ranging
from the infrared to x rays. He is an internationally recognized
leader in optical sciences, was educated at MIT, and has been
at Berkeley Lab for 20 years. In a transitional period over the
next year, Bob will be working together with ALS Science Advisor
Janos Kirz.
Finally,
Paul Alivisatos has asked ALS Special Assistant for Strategic
Initiatives, Pat Oddone, to assist him and his staff as he makes
the transition to Interim Laboratory Director. Pat is now stationed
in Building 50A, and it is expected that Pat's stay will last
a minimum of six to nine months. You might still see her around
the ALS from time to time as she continues to be involved in
ALS initiatives and Next Generation Light Source planning.
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Positive
Report from DOE Health, Safety, and Security Audit
As you all know, ALS was one of the divisions selected for the
recently concluded Department of Energy (DOE) Health, Safety, and
Security (HSS) audit. This was the most comprehensive safety inspection
Berkeley Lab has undergone in more than a decade. At the ALS alone,
more than 40 people were observed performing work, auditors sat
in on several of our safety meetings, and dozens of documents were
reviewed during the three weeks that they were here.
We
are very happy to report that HSS found all of our Integrated
Safety Management (ISM) Core Functions to be "effectively performed," the
top rating. This is an extremely positive result for our division
and we should be very proud of this accomplishment. We think
we've all come to realize the importance of safety, both as an
ethical and legal imperative, and for its impact to our scientific
mission. Safety is now an important part of generating confidence
on the part of our funders so reports such as this play a big role
in our ability to continue to succeed.
One comment in the report is especially
meaningful: "Division
management and staff displayed their commitment to teamwork and
safety in the development and implementation of hazard controls...." We
know how hard all of you have worked this last year and we have
seen your dedication and teamwork, so it is very gratifying to
see that this was also recognized by HSS. Your openness and willingness
to learn from this review went a long way towards achieving this
measure of recognition.
However, we should recognize that we still
have many areas that we can and need to improve upon. The appendices
to the report list many items that they found during their time
here and we all identified many more as a result of this process.
This report, however, clearly shows that we've accomplished much
and are on the right track. Many
thanks again to all of you.
Roger Falcone
Jim Floyd
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UEC
Corner: Save the Dates for 2009 ALS Users' Meeting
From meeting co-chairs David Osborn and Yayoi Takamura:

Make plans to attend the 2009 ALS Users' Meeting,
Thursday, October 15, through Saturday, October 17, 2009. This
year's meeting will be hosted jointly with the Molecular Foundry
and will have a primary focus on research to further the United
States' and the world's energy agenda. The meeting will have
plenary talks, workshops, a joint poster session, and vendor
exhibits. If you would like to organize a workshop for the 2009
Users' Meeting, please contact
Yayoi Takamura
or
David Osborn,
this year's meeting co-chairs. Check the meeting
Web site periodically
for the latest information, as it becomes available.
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Operations |
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For the user runs from January 21
to February 15, 2009, the beam reliability (time delivered/time
scheduled) was 95.9%. Of the scheduled beam, 88.7% was delivered
to completion. This includes the first week of user operations
in top-off mode. There were no significant interruptions.
For the user runs from February 18 to March 15, 2009, the beam
reliability was 96.0%. Of the scheduled beam, 89.7% was delivered
to completion. This includes two weeks of two-bunch operation
from March 4-15. There were no significant interruptions.
Questions about beam reliability
should be sent to David Richardson.
Requests
for special operations use of the "scrubbing" shift
should be sent to Rick Bloemhard (ALS-CR@lbl.gov, x4738).
Long-term and weekly operations schedules are available here. View the ring status in real time here.
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*Time delivered/time scheduled
**Percent of scheduled beam delivered without interruption
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